If you are looking to send email with attachment via shell script or at shell prompt/command line (read as bash prompt), use mutt command.
Mutt is a small but very powerful text based program for reading electronic mail under UNIX /Linux operating systems, including support for color terminals, MIME, and a threaded sorting mode.
Please note that mutt is a pure MUA and cannot send e-mail without proper email server . You need a working Mail Transfer Agent (MTA) such as sendmail or postfix. I am assuming that you have configured email server.